ECTS credits ECTS credits: 3
ECTS Hours Rules/Memories Student's work ECTS: 54 Hours of tutorials: 2 Expository Class: 12 Interactive Classroom: 7 Total: 75
Use languages Spanish, Galician
Type: Ordinary subject Master’s Degree RD 1393/2007 - 822/2021
Departments: Organic Chemistry
Areas: Organic Chemistry
Center Faculty of Chemistry
Call: Second Semester
Teaching: With teaching
Enrolment: Enrollable | 1st year (Yes)
At the end of the course the student will be able to:
Understand the fundaments of the catalytic cycles from a point of view of the reaction coordinates and the energy surfaces
Understand the variety of synthetic applications for the formation of bonds that involve organometallic compounds
Propose synthetic pathways that involve organometallic reagents in the key steps
1. Principles and energetic fundamentals of the organometallic catalytic cycles.
2. Cross coupling reactions and Heck reaction.
3. Insertion reactions.
4. Reactions of allyl-complexes
5. Reactions of organometallic complexes of alkenes, alkynes, dienes and arenes
6. Reactivity of carbenes
7. Reactions of activation of C-H bonds.
BASIC BIBLIOGRAPHY
• Bates, R. Organic Synthesis Using Transition Metals, 2nd Ed.; Wiley: Chichester, UK, 2012.
• Hegedus, L. S. Transition Metals in the Synthesis of Complex Organic Molecules, 2nd Ed.; University Science Books: Sausalito, CA, 1999
COMPLEMENTARY BIBLIOGRAPHY.
• Luther, G. W. (2016) Reactivity of Transition Metal Complexes: Thermodynamics, Kinetics and Catalysis, in Inorganic Chemistry for Geochemistry and Environmental Sciences: Fundamentals and Applications, John Wiley & Sons, Ltd, Chichester, UK. Doi: 10.1002/9781118851432. Capítulo 9.
• Cybulski, A.; Moulijn, J. A.; Stankiewicz, A. (2010) Novel Concepts in Catalysis and Chemical Reactors: Improving the Efficiency for the Future. WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. ISBN: 978-3-527-32469-9. Capítulo 1.
• Ananikov, V. P. (2015) Understanding Organometallic Reaction Mechanisms and Catalysis: Computational and Experimental Tools. Wiley-VCH Verlag GmbH & Co. KGaA. Published 2015 byWiley-VCH Verlag GmbH & Co. KGaA. Capítulo 9.
• Negishi, E., Ed. Handbook of Organopalladium Chemistry for Organic Synthesis; Wiley: New York, 2002
• De Meijere, A., Bräse, S., Oestreich, M. Metal-Catalyzed Cross-Coupling Reactions and More; Wiley-VCH: Weinheim, 2014.
• Beller, M., Bolm, C. Transition Metals for Organic Synthesis, 2nd Ed.; Wiley-VCH, Weinheim, 2004.
• Kazmaier, U. Transition Metal Catalyzed Enantioselective Allylic Substitution in Organic Synthesis, Springer-Verlag Berlin Heidelberg 2012.
• Crabtree, R. H. The Organometallic Chemistry of the Transition Metals, 4th Ed.; John Wiley & Sons, Wiley, 2005.
• Yu, J.-Q. Science of Synthesis: Catalytic Transformations via C-H Activation Vol. 1 & 2; Thieme.
GENERAL AND BASIC COMPETENCES
CG2 - To be able to gather and interpret data, information and relevant results, to draw conclusions and to issue reasoned reports on scientific, technological or other areas requiring the use of chemical knowledge.
CG5-To be able to use english terminology for arguing the experimental results in the context of chemistry
CG6- Apply correctly the new tecnologies of information for soving problems related to the profesional activity
CB6-Understand the originality of the knowledge for development or application of ideas in a research enviroment.
CB7 - The students should be able to apply the knowledge and the cappablilties to solve problems in new contexts including multidisciplinary enviroments
CB9 - The students should be able to communicate their conclusions and knowledge to specialized and non specialized public
CB10 - The student should posses the abilities to keep learning autonomously
TRANSVERSAL COMPETENCES
CT1 - To acquire skills for analysis and synthesis
CT3 - To develop capacity for autonomous work and efficiency within the research and profesional activity.
CT4 – To value the quality of continous improvement, acting with rigor, responsability and ethics.
SPECIFIC COMPETENCES
CE1 – Define concepts, principles, theories and facts for the different areas of Chemistry.
CE2 – Propose alternatives for the resolution of complex chemical problems
CE6 – Design processes which favor the treatment or the elimination of dangerous chemicals
CE8 – Analyze and use the data obtained in complex experments and to be able to relate them with chemical, physical or biological techniques
MD1. Theory classes. Lessons taught by the professor who may have different formats (theory, problems and / or general examples ...). The professor may have the support of audiovisual and computer media.
MD3. Seminars with professors or profesional from the industry, administration or other universities. Interactive sesions related with the different subjects with debates or interchange of opinions.
MD4. Theoretical / practical lessons in which applications of theory, problems, articles from literature ... are solved.
MD5. Tutorials in very small group:.
MD6. Individual or group projects about scientific themes related to the course
MD7. Dissertations..., including debates with professors and students
MD8. Using computer programs and internet. WebCT (Aula Virtual): The University of Santiago de Compostela uses a digital platform in which the teacher will provide the necessary information for students (PowerPoint files, summaries of the issues, newsletters, practice scripts, etc) via Internet.
MD10. Personal study based on different sources of information
MD11. Carry out different tests to asses the adquisition of theorical and practical knowledge
Contingency plan for remote teaching activities in the event that face-to-face classes are suspended:
They would be carried out synchronously / asynchronously and always according to the schedule established by the center, through the different telematic means available at the USC, preferably the Virtual Campus and Ms Teams.
To carry out tutorials, as well as to maintain direct communication both between the students themselves and between them and the teacher, they can be done through the Virtual Campus forum, through Ms. Teams or by email.
The scores for each student will be based on day-to-day work (40%) and the outcome of a final exam (60%).
Final exam [60 % of the final score, competences to evaluate CG6, CB6, CT3, CE1, CE2, CE4, CE6]
Resolution of problems [15 % of the final score, competences to evaluate CG2, CG5, CB7, CE2, CE4, CE6]
Dissertations (coursework, problems, practical cases, …). [5 %, competences CG2, CB9, CT1, CE8]
Attendance and participation. [10 %, competences CB10, CT4]
Day-to-day monitorization. [10 % , competences CG2, CT4]
"In cases of fraudulent performance of exercises or tests, the provisions of the" Regulations for evaluating the academic performance of students and reviewing grades "will apply.
Classroom
Lectures in large group, 12 h
Interactive clases in small group (seminars), 7 h
Interactive clases in very small group (tutorials) 2 h
Personal work
Individual self-study, 36 h
Preparation of written and oral presentations and activities in library or similar 18 h
Total working hours in the classroom 21 h
Total hours of personal work 54 h
CONTACT INFO:
Moisés Gulías Costa
ext 15790
moises.gulias [at] usc.es (moises[dot]gulias[at]usc[dot]es)
Ciqus building - Floor 3 - Office 5
Martín Fañanás Mastral
ext 15787
martin.fananas [at] usc.es (martin[dot]fananas[at]usc[dot]es)
Ciqus building - Floor 2 - Office 7
Moises Gulias Costa
Coordinador/a- Department
- Organic Chemistry
- Area
- Organic Chemistry
- Phone
- 881815790
- moises.gulias [at] usc.es
- Category
- Professor: University Lecturer
Martin Fañanas Mastral
- Department
- Organic Chemistry
- Area
- Organic Chemistry
- Phone
- 881815787
- martin.fananas [at] usc.es
- Category
- Professor: University Lecturer
| Wednesday | |||
|---|---|---|---|
| 11:00-13:00 | Grupo /CLE_01 | Spanish | Classroom 2.14 |
| 05.14.2025 16:00-20:00 | Grupo /CLE_01 | Classroom 2.12 |